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Passivation
- Nitric
The
term passivation is commonly applied to several distinctly different
operations or processes relating to stainless steels. In order to avoid
ambiguity in the setting of requirements, it may be necessary for the
purchaser to define precisely the intended meaning of passivation. Some
of the various meanings associated with the term passivation that are
in common usage include the following:
-
Passivation
is the process by which a stainless steel will spontaneously form
a chemically inactive surface when exposed to air or other oxygen-containing
environments. It was at one time considered that an oxidizing treatment
was necessary to establish this passive film, but it is now accepted
that this film will form spontaneously in an oxygen-containing environment
providing that the surface has been thoroughly cleaned or descaled.
- Passivation is
removal of exogenous iron or iron compounds from the surface of a stainless
steel by means of a chemical dissolution, most typically by a treatment
with an acid solution that will remove the surface contamination but
will not significantly affect the stainless steel itself...Unless otherwise
specified, it is this definition of passivation that is taken as the
meaning of a specified requirement for passivation." (ASTM A380)
This unit below is a Passivation System for medical components. The
standard A2PRR is constructed from type 316L stainless steel. The process
uses heated nitric acid. The line runs left to right.


PROCESS:
Passivation - The first stage is designed to remove
exogenous iron or iron compounds from the surface of the stainless steel
using nitric acid at 25% concentration in a 135 degree F heated immersion.
Due to the corrosive nature of the acid special consideration has been
given to the construction of the system. In addition to the 316L tank
and elevator construction the insulation panels, guards and legs have
been upgraded to 304 stainless. The elevator connecting arm and guide
rails have also been upgraded to 304 stainless on the passivation stage.
The electrical wiring is Nema4X (corrosion resistant) using fiberglass
enclosures and push button stations. A special alloy (Alloy 20Cb-3) heating
element is used for compatibility with the heated nitric acid.
Rinsing - The dual heated cascading rinses use platform
oscillation. The elevator moves the basket into the working zone and oscillates
the parts in solution with either a short or long stroke. A selector switched
is used to select either long 5 to 9 inch or short 2 to 4 inch strokes.
The long stroke is used to provide better flushing (hydraulically forcing
solution though the working zone) for nested masses of parts and/or complex
shapes with recessed passages whereas the short stroke is used to provide
quicker oscillations and faster cleaning of simple parts and/or part configurations.
Flexibility in stroke ranges and speeds produces more comprehensive cleaning.
Ventilation - A lip vent exhaust system is included
on the passivation stage. It is designed for 200 CFM per square foot of
opening. A slotted vent and large plenum extends across the front of the
processing chamber. The plenum extends along the side of the chamber and
terminates at the rear with a corrosion proof exhaust blower. The positive
mechanical ventilation is designed to limit the accumulation of chemical
vapors thereby making the system safer when the cover is open. Furthermore,
limiting the spreading of chemical vapors from the surface of the solution
to the surrounding area will lessen any hazard to the immediate environment.
Other
ACT systems to compliment Passivation:
- Degreasing
stages
- Precision
cleaning
- Ultrasonics
in the Passivating stage(s) and rinses
- Rinse quality
controls
- Automatic
Cascade Systems
- Efficient
dryers
- Roller transfer
- Custom fixtures
- Automated
transfer systems
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